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Atomic Perspectives Column

Universal Quantification — The Uncelebrated Strength of ICP-MS

May 1, 2009

Guest columnist Steven Wilbur discusses the elemental nature of ICP-MS and its strength as a universal quantifier, an aspect of the technique he believes has not received enough attention.

Hyphenated ICP-MS Techniques for Speciation Analysis

Mar 1, 2009

The authors discuss speciation analysis methods that enable scientists to identify and measure the quantities of one or more individual chemical species in a sample.

The Spectral Lines of Hydrogen

Nov 1, 2008

A short history of the early scientific developments related to the optical emission lines of hydrogen is presented. These were crucial to the development of the quantum theory. Balmer's empirical formula was an important milestone. Rydberg and others provided additional work, especially for higher atomic numbers. However, it remained for Bohr to provide the physical reasoning.

Wilhelm Conrad Röntgen and the Discovery of X-Rays

Jul 1, 2008

Volker Thomsen takes a look at the impact that the discovery of X-rays by Wilhelm Röntgen in 1895 has had on the world.

A Pragmatic Approach to Managing Interferences in ICP-MS

May 1, 2008

While inductively coupled plasma-mass spectrometry (ICP-MS) is capable of part-per-quadrillion (ppq) detection limits under ideal conditions, most applications do not require this level of sensitivity and do not justify the cost associated with achieving it. Practical sensitivity in ICP-MS is determined not by instrument signal-to-noise ratio, but rather by controlling interferences and matrix effects in real samples. Understanding the sources of these effects and their management is critical in determining the most practical way to achieve specific data quality objectives.

Innovations in Speciation Analysis Using HPLC with ICP-MS Detection

Apr 1, 2008

Speciation analysis has grown rapidly and has expanded to a variety of markets, including environmental, clinical, food, nutraceutical, and bioanalytical. This growth has resulted from the realization that knowing the total amount of an element does not always provide adequate information for assessing health and environmental effects, but knowing which form of the element is present presents a much more comprehensive picture.

Quantitative Analysis of Low Levels of Chlorine and Iron in Hydraulic Oil Samples

Mar 1, 2006

Simple, fast, and reliable on-site hydraulic oil analysis should be an integral part of any preventative maintenance program. Since the majority of machine failures are contamination related, it is important to analyze the hydraulic fluid to monitor equipment condition and identify machine wear. Significant cost savings can result from early identification of machine failure, oil quality, handling and other problems. Oil analysis can detect changes in oil quality, contamination, wear and chemical differences. Benefits of this information include prolonged equipment life, reduced equipment downtime, and reduced overall maintenance costs. In addition, plants can increase intervals between oil changes, thus reducing waste oil, maintenance, and oil purchase costs.

RoHS/WEEE Application of a Miniature X-Ray Spectrometer

Mar 1, 2006

The RoHS/WEEE directive requires the electronics industry to certify that products comply with maximum concentration amounts of particular elements and compounds (Cr VI, Pb, Cd, Hg, Br PBB/PBDE) by July 2006. Instrumentation must be developed to perform the certification.

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